The reaction $CH _{3} COF + H _{2} O \quad \rightleftharpoons CH _{3} COOH + HF$
Condition $I$ $:$ $\left[ H _{2} O \right]_{0}=1.00 \,M$
$\left[ CH _{3} COF \right]_{0}=0.01 \,M$
Condition $II$ $:$ $\left[ H _{2} O \right]_{0}=0.02 \,M$
$\left[ CH _{3} COF \right]_{0}=0.80 \,M$
Condition - $I$ | Condition - $II$ | ||
Time $min$ |
$\left[ CH _{3} COF \right]$ $M$ |
Time $min$ |
$\left[ H _{2} O \right] \,M$ |
$0$ | $0.01000$ | $0$ | $0.0200$ |
$10$ | $0.00867$ | $10$ | $0.0176$ |
$20$ | $0.00735$ | $20$ | $0.0156$ |
$40$ | $0.00540$ | $40$ | $0.0122$ |
Determine the order of reaction and calculate rate constant.
$(i)$ Reaction is pseudo $1^{\text {st }}$ reaction, in which $\left[\mathrm{H}_{2} \mathrm{O}\right]$ is constant.
$(ii)$ Reaction is pseudo $1^{\text {st }}$ reaction, but in order to this reaction $=2$.
A reaction was found to be second order with respect to the concentration of carbon monoxide. If the concentration of carbon monoxide is doubled, with everything else kept the same, the rate of reaction will
The rate of a gaseous reaction is given by the expression $K\,[A]\,[B]$. If the volume of the reaction vessel is suddenly reduced to $1/4^{th} $ of the initial volume, the reaction rate relating to original rate will be
For the reaction $A + B \rightarrow$ products, it is observed that
$(i)\,\,$on doubling the initial concentration of $A$ only, the rate of reaction is also doubled and
$(ii)$ on doubling the initial concentration of both $A$ and $B,$ there is a change by a factor of $8$ in the rate of the reaction.
The rate of this reaction is given by
From the rate expression for the following reactions, determine their order of reaction and the dimensions of the rate constants.
$(i)$ $3 NO ( g ) \rightarrow N _{2} O$ $(g)$ Rate $=k[ NO ]^{2}$
Reaction : $KCl{O_3} + 6FeS{O_4} + 3{H_2}S{O_4} \to $ $KCl + 3F{e_2}{\left( {S{O_4}} \right)_3} + 3{H_2}O$
Which is True $(T)$ and False $(F)$ in the following sentence ?
The reaction is elementary.